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Recent progress in coordination chemistry, photo-physical properties, and applications of pyridine-based Cu(I) complexes

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Version 2 2018-11-18, 11:13
Version 1 2018-08-14, 07:10
journal contribution
posted on 2018-11-18, 11:13 authored by Rashid Ilmi, Idris Juma Al-busaidi, Ashanul Haque, Muhammad S. Khan

Copper(I) [Cu(I)] complexes offer cheap and alternative materials for several real-life applications. Pyridine (Py), bipyridine (Bpy), and related analogues have strong donating ability with propensity to ease functionalization via modern synthetic protocols. A large number of Cu(I) complexes/clusters/polymers bearing functionalized Py-based ligands have emerged with rich coordination chemistry, fascinating structures, and intriguing photo-physical properties. This article sheds light on recent advances in the coordination chemistry and photophysical properties of Cu(I) complexes/clusters/polymers and their applications in the areas of optoelectronics (OE) (light emitting devices [LEDs] and dye-sensitized solar cells [DSSCs]) and sensing (aliphatic and aromatic gases).

Funding

MSK thanks His Majesty’s Trust Fund for Strategic Research (Grant No. SR/SQU/SCI/CHEM/16/02) for funding. MSK also acknowledges The Research Council (TRC), Oman and HM’s Trust Fund, Oman for post-doctoral fellowships to AH and RI, respectively, and for Ph.D. scholarship to IJA.

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