Preparation and Characterization of Persistent Maltose-Conjugated Triphenylmethyl Radicals
2016-02-22T08:09:42Z (GMT) by
The condensation reaction of d-maltose to free radicals of the series of tris(2,4,6-trichlorophenyl)methyl (TTM) and tris(perchlorophenyl)methyl (PTM) has been described for the first time. The new persistent radicals <b>1</b> and <b>2</b> are very stable and have been characterized by EPR. Their cyclic voltammograms show a quasi-reversible process in the cathode, being reduced to the corresponding anions, with redox potentials a little lower than those of TTM and PTM, respectively. Their oxidant activity is in close relation with their reduction potentials. Therefore, while <b>2</b> is reduced by ascorbic acid, <b>1</b> remains unaltered.