ma7b00982_si_001.pdf (4.8 MB)
Nanoemulsions and Nanolatexes Stabilized by Hydrophobically Functionalized Cellulose Nanocrystals
journal contribution
posted on 2017-08-09, 21:19 authored by Yefei Zhang, Vahid Karimkhani, Brian T. Makowski, Gamini Samaranayake, Stuart J. RowanCarboxylic acid cellulose
nanocrystals (CNC-COOHs) that have been
covalently functionalized (via peptide coupling chemistry) with a
range of different hydrophobic groups have been investigated as nanoparticle
surfactants to stabilize styrene-in-water nanoemulsions. It is shown
that the size and stability of these nanoemulsions depend on both
the amount of surface carboxylic acid groups as well as the amount
and type of hydrophobic alkyl groups on the CNC surface. Two different
biosources for the CNCs, microcrystalline cellulose (MCC) and Miscanthus x. Giganteus (MxG), were investigated to see
the effect that the CNC aspect ratio has on these nanoemulsions. Stable
oil-in-water (o/w) Pickering emulsions with particle diameters of
only a few hundred nanometers can be accessed using these hydrophobic
functionalized CNCs, and the resulting emulsions can be polymerized
to access nanometer sized latexes. The hydrophobic/hydrophilic balance
of the functionalized CNCs was found to be critical to lower the interfacial
tension between oil and water, which allowed access to stable emulsions
with droplet diameters <1 μm. The ability to stabilized nanosized
emulsions and latexes extends the potential of CNCs as green surfactants
for numerous technological applications, such as food, cosmetics,
drug delivery systems, and coatings.