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Highly Efficient Antimonate Removal from Water by Pyrite/Hematite Bi-Mineral: Performance and Mechanism Studies
journal contribution
posted on 2019-11-08, 19:48 authored by Xingyu He, Xiaobo Min, Tianyu Peng, Yong Ke, Feiping Zhao, Yunyan Wang, Mika SillanpääPyrite/hematite bi-mineral (FeS2/α-Fe2O3) was obtained by thermal
modification of pyrite. FeS2/α-Fe2O3 was investigated and
developed as a promising adsorbent for antimonate [Sb(V)] removal.
The influence of initial concentration, temperature, initial pH, contact
time, and coexisting anions on Sb(V) adsorption performance of FeS2/α-Fe2O3 was investigated. FeS2/α-Fe2O3 exhibited good adsorption
performance and excellent removal efficiency. The results of the Langmuir
isotherm model indicated that FeS2/α-Fe2O3 had a large adsorption capacity (347.2 mg/g) for Sb(V)
removal from water. High removal efficiency by FeS2/α-Fe2O3 was achieved over a broad pH range (2.5–10.7).
The coexisting anions had little influence on Sb(V) adsorption by
FeS2/α-Fe2O3. The pseudo-second-order
and Dubinin–Radushkevich model analyses (E = 12.62 kJ/mol) suggested that FeS2/α-Fe2O3’s Sb(V) removal process was chemisorption. The
negative Gibbs free energy change and endothermic enthalpy change
of 5.00 kJ/mol indicated that Sb(V) adsorption by FeS2/α-Fe2O3 was feasible, endothermic, and spontaneous.
Additionally, Fourier transform infrared spectroscopy and X-ray photoelectron
spectroscopy analyses indicated that Sb(V) formed an inner-sphere
complex on thiol groups and hydroxyl groups surface sites on the surface
of FeS2/α-Fe2O3. At last, the
real environmental water application also confirmed the excellent
adsorption performance of FeS2/α-Fe2O3. From a practical viewpoint, FeS2/α-Fe2O3 can be a hopeful alternative for the remediation
of Sb(V) pollution because of its large uptake capacity, low-cost,
reusability, and easy availability.