(Spectro)electrochemical and Electrocatalytic Investigation
of 1,1′-Dithiolatoferrocene–Hexacarbonyldiiron
Version 2 2019-01-18, 18:50
Version 1 2019-01-17, 16:18
Posted on 2019-01-18 - 18:50
Hexacarbonyldiiron
bridged by a 1,1′-dithiolatoferrocene, [Fe(C5H4S)2{Fe(CO)3}2] (1), was synthesized, and the electrochemistry showed reversible oxidation
at the Fe(C5H4S)2 site and quasi-reversible
reduction at the hexacarbonyldiiron site. Spectroelectrochemical techniques
showed reduction-induced ligand isomerization, where the thiolate
ligand went from bridging to terminal and one carbon monoxide ligand
moved to a quasi-bridging position; this mechanism was further supported
by cyclic voltammetry simulation and density functional theory calculations.
Complex 1 showed electrocatalytic activity toward hydrogen-evolving
reaction.
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Häßner, Manuel; Fiedler, Jan; Ringenberg, Mark R. (2019). (Spectro)electrochemical and Electrocatalytic Investigation
of 1,1′-Dithiolatoferrocene–Hexacarbonyldiiron. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.8b02971
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AUTHORS (3)
MH
Manuel Häßner
JF
Jan Fiedler
MR
Mark R. Ringenberg
KEYWORDS
thiolate ligandElectrocatalytic Investigationtheory calculationshexacarbonyldiiron sitequasi-bridging positionFequasi-reversible reductioncyclic voltammetry simulation2 siteelectrocatalytic activityhydrogen-evolving reactionSpectroelectrochemical techniquesComplex 1reduction-induced ligand isomerizationcarbon monoxide ligand