Utilization of Biomass Fly Ash for Improving Quality
of Organic Dye-Contaminated Water
Posted on 2020-06-22 - 19:43
Development
of innovative methodologies to convert biomass ash
into useful materials is essential to sustain the growing use of biomass
for energy production. Herein, a simple chemical modification approach
is employed to functionalize biomass fly ash (BFA) with 3-aminopropyltriethoxy
silane (APTES) to develop an inexpensive and efficient adsorbent for
water remediation. The amine-functionalized BFA (BFA–APTES)
was fully characterized by employing a range of characterization techniques.
Adsorption behavior of BFA–APTES was evaluated against two
anionic dyes, namely, alizarin red S (ARS) and bromothymol blue (BTB).
In the course of experimental data analysis, the computation tools
of data fitting for linear and nonlinear form of Langmuir, Freundlich,
and the modified Langmuir–Freundlich adsorption isotherms were
used with the aid of Matlab R2019b. In order to highlight the misuse
of linearization of adsorption models, the sum of the squares of residues
(SSE) values obtained from nonlinear models are compared with R2 values obtained from the linear regression.
The accuracy of the data fitting was checked by the use of SSE as
an error function instead of the coefficient of determination, R2. The dye adsorption capacity of BFA–APTES
was also compared with the nonfunctionalized BFA. The maximum adsorption
capacities of BFA–APTES for ARS and BTB dye molecules were
calculated to be around 13.42 and 15.44 mg/g, respectively. This value
is approximately 2–3 times higher than the pristine BFA. A
reasonable agreement between the calculated and experimental values
of qe obtained from the nonlinear form
of kinetic models verified the importance of using equations in their
original form. The experimentally calculated thermodynamic parameters
including molar standard Gibbs free energy (ΔadGm0) and molar standard enthalpy change (ΔadHm0) reflected that the process of adsorption of dye molecules on the
BFA–APTES adsorbent was spontaneous and exothermic in nature.
Moreover, the used BFA–APTES adsorbent could be regenerated
and reused for several cycles with significant dye adsorption capacity.
The remediation capability of the BFA–APTES adsorbent against
ARS dye was also demonstrated by packing a small column filled with
the BFA–APTES adsorbent and passing a solution of ARS through
it. Overall, we provide a simple and scalable route to convert BFA
into an efficient adsorbent for water remediation applications.
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Dogar, Safana; Nayab, Sana; Farooq, Muhammad Qamar; Said, Amir; Kamran, Raheel; Duran, Hatice; et al. (1753). Utilization of Biomass Fly Ash for Improving Quality
of Organic Dye-Contaminated Water. ACS Publications. Collection. https://doi.org/10.1021/acsomega.0c00889
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AUTHORS (7)
SD
Safana Dogar
SN
Sana Nayab
MF
Muhammad Qamar Farooq
AS
Amir Said
RK
Raheel Kamran
HD
Hatice Duran
BY
Basit Yameen