Total Synthesis of the Proposed Structure of Penasulfate
A: l‑Arabinose as a Source of Chirality

Zhang, Yongmin

Total Synthesis of the Proposed Structure of Penasulfate A: l‑Arabinose as a Source of Chirality

Posted on 2019-06-26 - 15:36

The total synthesis of putative penasulfate A was effectively achieved by a convergent strategy with a longest linear sequence of 14 steps and overall yield of 8.6%. The highlights of our strategy involved an E-selective olefin cross-metathesis, Suzuki cross-coupling, and a copper(I)-catalyzed coupling reaction.

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Gao, Yangguang; Cao, Zhou; Zhang, Qiang; Guo, Rui; Ding, Fei; You, Qingliang; et al. (2019). Total Synthesis of the Proposed Structure of Penasulfate A: l‑Arabinose as a Source of Chirality. ACS Publications. Collection. https://doi.org/10.1021/acs.jnatprod.9b00245

https://doi.org/10.1021/acs.jnatprod.9b00245

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