Synthesis of Alkaline Anion Exchange Membranes with
Chemically Stable Imidazolium Cations: Unexpected Cross-Linked Macrocycles
from Ring-Fused ROMP Monomers
Version 2 2018-04-13, 18:20
Version 1 2018-04-13, 18:18
Posted on 2018-04-13 - 18:20
In
order to prepare base-stable, mechanically strong, and synthetically
feasible alkaline anion exchange membranes (AAEMs) for applications
in alkaline fuel cells, an imidazolium-fused cyclooctene monomer was
prepared and subjected to ring-opening metathesis polymerization (ROMP)
conditions. Surprisingly, macrocyclic oligomers were obtained instead
of high molecular weight polymers. High-performance AAEMs were synthesized
by using a bifunctional monomer to cross-link the macrocycles. The
resultant AAEMs showed high ionic conductivities (σOH– = 59 mS/cm at 50 °C), robust mechanical
properties, and excellent alkaline stabilities.
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You, Wei; Hugar, Kristina M.; Coates, Geoffrey W. (2018). Synthesis of Alkaline Anion Exchange Membranes with
Chemically Stable Imidazolium Cations: Unexpected Cross-Linked Macrocycles
from Ring-Fused ROMP Monomers. ACS Publications. Collection. https://doi.org/10.1021/acs.macromol.8b00209
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AUTHORS (3)
WY
Wei You
KH
Kristina M. Hugar
GC
Geoffrey W. Coates
KEYWORDS
weight polymersfuel cellsUnexpected Cross-Linked MacrocyclesChemically Stable Imidazolium Cationsbifunctional monomerHigh-performance AAEMsanion exchange membranesring-opening metathesis polymerizationRing-Fused ROMP Monomersmacrocyclic oligomersOHimidazolium-fused cyclooctene monomerAlkaline Anion Exchange Membranes