Synthesis
and Reactivity of a Transient, Terminal
Nitrido Complex of Rhodium
Posted on 2013-11-27 - 00:00
Irradiation
of rhodium(II) azido complex [Rh(N3){N(CHCHPtBu2)2}] allowed for the spectroscopic
characterization of the first reported rhodium complex with a terminal
nitrido ligand. DFT computations reveal that the unpaired electron
of rhodium(IV) nitride complex [Rh(N){N(CHCHPtBu2)2}] is located in an antibonding Rh–N π*
bond involving the nitrido moiety, thus resulting in predominant N-radical
character, in turn providing a rationale for its transient nature
and observed nitride coupling to dinitrogen.
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Scheibel, Markus
G.; Wu, Yanlin; Stückl, A. Claudia; Krause, Lennard; Carl, Elena; Stalke, Dietmar; et al. (2016). Synthesis
and Reactivity of a Transient, Terminal
Nitrido Complex of Rhodium. ACS Publications. Collection. https://doi.org/10.1021/ja409764j
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AUTHORS (8)
MS
Markus
G. Scheibel
YW
Yanlin Wu
AS
A. Claudia Stückl
LK
Lennard Krause
EC
Elena Carl
DS
Dietmar Stalke
BB
Bas de Bruin
SS
Sven Schneider