Synthesis and Physical Study of Perylene and Anthracene
Polynitrile as Electron Acceptors
Posted on 2019-07-10 - 20:43
Attaching electron-withdrawing
nitrile groups to π-conjugated
systems is an effective approach toward electron acceptors. By combining
various cyanation methodologies, perylene and anthracene polynitriles
with up to eight nitrile substituents on one aromatic scaffold were
synthesized. This strategy produces stable electron acceptors with
lowest unoccupied molecular orbital (LUMO) levels comparable to benchmark
acceptors. A very stable octanitrile anion was also produced serendipitously.
Reactivity patterns of these acceptors were rationalized by density
functional theory (DFT) calculation.
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Li, Ting-Yu; Lin, Yi-Chun; Song, Yu-Huei; Lu, Hsiu-Feng; Chao, Ito; Lin, Chih-Hsiu (2019). Synthesis and Physical Study of Perylene and Anthracene
Polynitrile as Electron Acceptors. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.9b01454