Synthesis and Characterization of a Boron–Nitrogen−Boron
Zigzag-Edged Benzo[fg]tetracene Motif

Bettinger, Holger F.

Synthesis and Characterization of a Boron–Nitrogen−Boron Zigzag-Edged Benzo[fg]tetracene Motif

Posted on 2017-08-16 - 13:26

The boron–nitrogen−boron (BNB) zigzag edged benzo[fg]tetracene is accessible from 4-butyl-2,6-diphenylaniline in four steps in good yields. The two mesityl groups stabilize the boron centers toward nucleophilic attack and result in two enantiomeric forms in the solid state. The title compound has a large optical gap, shows blue fluorescence, and is quite resistant toward oxidation and reduction.

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Fingerle, Michael; Maichle-Mössmer, Cäcilia; Schundelmeier, Simon; Speiser, Bernd; Bettinger, Holger F. (2017). Synthesis and Characterization of a Boron–Nitrogen−Boron Zigzag-Edged Benzo[fg]tetracene Motif. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b01873

https://doi.org/10.1021/acs.orglett.7b01873

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