Supplementary material from "Petrophysical characterization of high-rank coal by nuclear magnetic resonance: a case study of the Baijiao coal reservoir, SW China"

To better apply nuclear magnetic resonance (NMR) to evaluate the petrophysical characterization of high-rank coal, six anthracite samples from the Baijiao coal reservoir were measured by NMR. The porosity, T₂ cutoff value, permeability and pore type were analysed using the transverse relaxation time (T₂) spectrum before and after centrifugation. The results show that the T₂ spectrum of water-saturated anthracite can be divided into a discontinuous and continuous trimodal distribution. According to the connectivity among pores, three T₂ spectrum peaks were identified at the relaxation times of 0.01–1.7 ms, 1.7–65 ms and greater than 65 ms, which correspond to the micropores (less than 100 nm), mesopores (100–1000 nm) and macropores (greater than 1000 nm), respectively. Based on the T₂ cutoff value, we divided the T₂ spectrum into two parts: bound fluid and free fluid. By comparing two classic permeability models, we proposed a permeability model to calculate the permeability of anthracite. This result demonstrates that NMR has a great significance to the exploration of coal reservoirs and to the understanding of the development of coalbed methane.