Structural Revision
and Absolute Configuration of
Burnettramic Acid A
Posted on 2019-12-12 - 19:06
The recently discovered antibiotic burnettramic acid
A (1) and three new congeners, burnettramic acids C–E
(2–4), were identified from the co-cultures
of
two marine Aspergillus strains. The structure of
burnettramic acid A was revised on the basis of reinterpretation of
the nuclear magnetic resonance (NMR) data and chemical derivatization.
The full absolute configurations of burnettramic acids were established
using the Mosher ester method and Marfey’s analysis, combined
with density functional theory calculation of NMR and electric circular
dichroism data.
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Li, Jiao; Chen, Minghua; Hao, Xiaomeng; Li, Shasha; Li, Fang; Yu, Liyan; et al. (2019). Structural Revision
and Absolute Configuration of
Burnettramic Acid A. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.9b04008
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AUTHORS (8)
JL
Jiao Li
MC
Minghua Chen
XH
Xiaomeng Hao
SL
Shasha Li
FL
Fang Li
LY
Liyan Yu
CX
Chunling Xiao
MG
Maoluo Gan