Solar Photocatalytic Phenol Polymerization and Hydrogen
Generation for Flocculation of Wastewater Impurities
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Posted on 2019-06-04 - 16:41
Achieving global
sustainability will require balancing encroaching
climate changes while maintaining the existing quality of life. Using
sunlight to purify wastewater while simultaneously generating usable
fuels is an opportunity to approach both targets in a cost-efficient
manner. In addition, converting biomass products to usable polymers
is a sustainable approach for potentially replacing polystyrene or
other petroleum-derived polymers. Phenols from medical, manufacturing,
and agricultural waste are commonly found in many water sources, and
they are known to foul common reverse osmosis membranes. Here, we
show oxidative polymerization of guaiacol, an aromatic compound derived
from biomass, with concurrent hydrogen gas generation by using platinum-seeded
cadmium sulfide nanorods (Pt@CdS) as photocatalysts. Rather than forming
short oligomers as typically made by enzymes such as laccase and peroxidase,
the resulting polymers show higher molecular weights that can more
easily flocculate out of water. By comparing guaiacol conversion to
molecular weight and dispersity, we found the guaiacol to polymerize
via a chain-growth process. We also show that Pt@CdS can polymerize
other phenols as well by testing the monomers phenol, 2,6-dihydroxybenzoic
acid, gallic acid, and vanillin. Lastly, because the aqueous solubility
of these aromatic polymers decreases dramatically with molecular weight,
polymerization reactions were also tested in biphasic solutions to
determine whether chain growth could propagate in the oil phase. We
show that the Pt@CdS nanoparticles can form stable Pickering emulsions
in various biphasic combinations and that both H2 formation
and polymer molecular weight correlated to the partition coefficient
of guaiacol into the oil phase as well as the solubility of the growing
polymer chains. These combined studies demonstrate the possibility
of using nanoscale photocatalysts to oxidatively polymerize phenolic
substrates via a chain-growth mechanism, thereby providing a path
for pretreating water by flocculating out contaminants with concurrent
generation of hydrogen.
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Hafenstine, Glenn
R.; Patalano, Ryan E.; Harris, Alexander W.; Jiang, Grace; Ma, Ke; Goodwin, Andrew P.; et al. (2019). Solar Photocatalytic Phenol Polymerization and Hydrogen
Generation for Flocculation of Wastewater Impurities. ACS Publications. Collection. https://doi.org/10.1021/acsapm.9b00210