Silver-Catalyzed Minisci Reactions Using Selectfluor
as a Mild Oxidant

Baxter, Ryan D.

Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant

Posted on 2017-10-18 - 14:18

A new method for silver-catalyzed Minisci reactions using Selectfluor as a mild oxidant is reported. Heteroarenes and quinones both participate in radical C–H alkylation and arylation from a variety of carboxylic and boronic acid radical precursors. Several oxidatively sensitive and highly reactive radical species are successful, providing structures that are challenging to access by other means.

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Galloway, Jordan D.; Mai, Duy N.; Baxter, Ryan D. (2017). Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b02706

https://doi.org/10.1021/acs.orglett.7b02706

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