Rhodium-Catalyzed Asymmetric Cyclization/Addition
Reactions of 1,6-Enynes and Oxa/Azabenzonorbornadienes
Version 2 2018-02-12, 21:04
Version 1 2018-02-12, 05:33
Posted on 2018-02-12 - 21:04
A mild, efficient, and novel rhodium
catalyzed asymmetric cyclization–addition
domino reaction of oxa/azabenzonorbornadienes and 1,6-enynes is documented.
Through the use of a [Rh(COD)2]BF4-(R)-An-SDP catalytic system, highly enantioenriched cyclization–addition
products were obtained in good yields and with excellent enantioselectivities.
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Zhou, Yongyun; Yu, Lu; Chen, Jingchao; Xu, Jianbin; He, Zhenxiu; Shen, Guoli; et al. (2018). Rhodium-Catalyzed Asymmetric Cyclization/Addition
Reactions of 1,6-Enynes and Oxa/Azabenzonorbornadienes. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b04044
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AUTHORS (7)
YZ
Yongyun Zhou
LY
Lu Yu
JC
Jingchao Chen
JX
Jianbin Xu
ZH
Zhenxiu He
GS
Guoli Shen
BF
Baomin Fan