Rhodium-Catalyzed Asymmetric Cyclization/Addition Reactions of 1,6-Enynes and Oxa/Azabenzonorbornadienes

Published on 2018-02-12T21:04:57Z (GMT) by
A mild, efficient, and novel rhodium catalyzed asymmetric cyclization–addition domino reaction of oxa/azabenzonorbornadienes and 1,6-enynes is documented. Through the use of a [Rh­(COD)<sub>2</sub>]­BF<sub>4</sub>-(<i>R</i>)-An-SDP catalytic system, highly enantioenriched cyclization–addition products were obtained in good yields and with excellent enantioselectivities.

Cite this collection

Zhou, Yongyun; Yu, Lu; Chen, Jingchao; Xu, Jianbin; He, Zhenxiu; Shen, Guoli; Fan, Baomin (2018): Rhodium-Catalyzed Asymmetric Cyclization/Addition

Reactions of 1,6-Enynes and Oxa/Azabenzonorbornadienes. ACS Publications.