Rhodium-Catalyzed [4 + 3] Annulations of Sulfoximines
with α,β-Unsaturated Ketones Leading to 1,2-Benzothiazepine
1‑Oxides

Bolm, Carsten

Rhodium-Catalyzed [4 + 3] Annulations of Sulfoximines with α,β-Unsaturated Ketones Leading to 1,2-Benzothiazepine 1‑Oxides

Posted on 2017-10-18 - 20:18

A Cp*Rh(III) complex has been used as catalyst for the preparation of unprecedented 1,2-benzothiazepine 1-oxides by [4 + 3] cyclization of NH-sulfoximines with α,β-unsaturated ketones. For a wide range of substrates with various functional groups, moderate to good product yields were obtained.

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Wen, Jian; Cheng, Hanchao; Raabe, Gerhard; Bolm, Carsten (2017). Rhodium-Catalyzed [4 + 3] Annulations of Sulfoximines with α,β-Unsaturated Ketones Leading to 1,2-Benzothiazepine 1‑Oxides. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b03106

https://doi.org/10.1021/acs.orglett.7b03106

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