Resolving the (19R) Absolute Configuration
of Lanciferine, a Monoterpene
Indole Alkaloid from Alstonia boulindaensis
Posted on 2018-02-20 - 20:36
Reinvestigation of the structure
of lanciferine (1a) through extensive spectroscopic analysis
in conjunction with a
detailed computational study led to the unambiguous assignment of
its (19R) absolute configuration, thus leading to
the full (2R, 3S, 7S, 15R, 16R, 19R, 20S) assignment of lanciferine 45 years after
its isolation.
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Beniddir, Mehdi A.; Genta-Jouve, Grégory; Lewin, Guy (2018). Resolving the (19R) Absolute Configuration
of Lanciferine, a Monoterpene
Indole Alkaloid from Alstonia boulindaensis. ACS Publications. Collection. https://doi.org/10.1021/acs.jnatprod.7b00957
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AUTHORS (3)
MB
Mehdi A. Beniddir
GG
Grégory Genta-Jouve
GL
Guy Lewin