Power-to-Gas through High Temperature Electrolysis
and Carbon Dioxide Methanation: Reactor Design and Process Modeling
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Posted on 2018-03-15 - 17:19
This
work deals with the coupling between high temperature steam
electrolysis using solid oxide cells (SOEC) and carbon dioxide methanation
to produce a synthetic natural gas (SNG) directly injectable in the
natural gas distribution grid via a power-to-gas (P2G) pathway. An
intrinsic kinetics obtained from the open literature has been used
as the basis for a plug flow reactor model applied to a series of
cooled multitube fixed bed reactors for methane synthesis. Evaporating
water has been considered as coolant, ensuring a high heat transfer
coefficient within the shell side of the reactor. A methanation section
has been designed and optimized in order to moderate the maximum temperature
within the catalytic bed and to minimize the catalyst load. Then,
process modeling of a plant coupling high temperature electrolysis
and methanation is presented: the main goal of this analysis is the
calculation of overall plant efficiency (in terms of electricity-to-SNG
chemical energy). Plant size has been set considering a 10 MWel SOEC-based electrolysis unit; heat produced from the exothermal
methanation is entirely used for water evaporation before the steam
electrolysis. A heat exchanger network (HEN) has been designed in
order to reduce the number of components, resulting in an external
heat requirement equal to 185 kW (≈1.9% of the electrolysis
power). The SOEC-based power-to-gas system presented a higher heating
value based efficiency equal to ≈86% (≈77% if evaluated
on lower heating value basis).
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Giglio, Emanuele; Deorsola, Fabio Alessandro; Gruber, Manuel; Harth, Stefan Raphael; Morosanu, Eduard Alexandru; Trimis, Dimosthenis; et al. (2018). Power-to-Gas through High Temperature Electrolysis
and Carbon Dioxide Methanation: Reactor Design and Process Modeling. ACS Publications. Collection. https://doi.org/10.1021/acs.iecr.8b00477