Photoredox Generation of Sulfonyl Radicals and Coupling
with Electron Deficient Olefins
Version 2 2020-07-15, 19:47
Version 1 2020-06-25, 22:43
Posted on 2020-07-15 - 19:47
Various sulfone tetrazoles were activated
via iridium photoredox
catalysis in the presence of DMAP to give dialkyl sulfones. The presumed
sulfone radical intermediates were trapped by a range of electron-deficient
olefins in generally good to excellent yields.
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Chen, Yiding; McNamara, Nicole; May, Oliver; Pillaiyar, Thanigaimalai; Blakemore, David C.; Ley, Steven V. (2020). Photoredox Generation of Sulfonyl Radicals and Coupling
with Electron Deficient Olefins. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.0c01730
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AUTHORS (6)
YC
Yiding Chen
NM
Nicole McNamara
OM
Oliver May
TP
Thanigaimalai Pillaiyar
DB
David C. Blakemore
SL
Steven V. Ley