Pd-Catalyzed Enantio- and Regioselective Formation
of Allylic Aryl Ethers

Kleij, Arjan W.

Pd-Catalyzed Enantio- and Regioselective Formation of Allylic Aryl Ethers

Posted on 2017-11-18 - 15:29

A general methodology for the synthesis of enantioenriched tertiary allylic aryl ethers through Pd-catalyzed decarboxylative reactions of vinyl cyclic carbonates and phenols is presented. Switching of the regioselectivity toward the formation of linear products by a judicious choice of the ligand is also reported.

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Xie, Jianing; Guo, Wusheng; Cai, Aijie; Escudero-Adán, Eduardo C.; Kleij, Arjan W. (2017). Pd-Catalyzed Enantio- and Regioselective Formation of Allylic Aryl Ethers. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b03247

https://doi.org/10.1021/acs.orglett.7b03247

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