Oxidative Degradation of Multi-Carbon Substrates by
an Oxidic Cobalt Phosphate Catalyst
Posted on 2018-06-22 - 15:18
The
development of heterogeneous catalysts to affect the activation of recalcitrant biomolecules
has applications for biomass processing, biomass fuel cells, and wastewater
remediation. We demonstrate that a cobalt oxygen evolution catalyst
(Co-OEC) can catalyze the oxidation of carbon feedstocks completely
to CO2. A quantitative analysis of the product distribution
from the oxidative degradation of the C2 compound, ethylene
glycol, is elaborated and a reaction sequence is proposed. The Co-OEC
is also found to be competent for oxidatively degrading C2+ compounds, including glucose and lignin, to carbon dioxide at consequential
Faradaic efficiencies.
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Keane, Thomas
P.; Brodsky, Casey N.; Nocera, Daniel G. (2018). Oxidative Degradation of Multi-Carbon Substrates by
an Oxidic Cobalt Phosphate Catalyst. ACS Publications. Collection. https://doi.org/10.1021/acs.organomet.8b00337
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AUTHORS (3)
TK
Thomas
P. Keane
CB
Casey N. Brodsky
DN
Daniel G. Nocera
KEYWORDS
glucoseFaradaic efficienciesbiomoleculecarbon dioxidecatalyzeethylene glycolCo-OECcobalt oxygen evolution catalystoxidative degradationreaction sequenceapplicationMulti-Carbon Substratesligninoxidationbiomass processingactivationoxidativelyOxidic Cobalt Phosphate CatalystCO 2C 2 compoundefficiencyOxidative Degradationcarbon feedstockswastewater remediationbiomass fuel cellsanalysisproduct distribution