Oligosilanyl-Bridged Biscarbazoles:
Structure, Synthesis, and Spectroscopic Properties
Posted on 2020-07-21 - 11:34
Oligosilanyl-bridged
systems are expected
to give rise to unique optoelectronic properties because of σ–π
conjugation between the Si–Si σ orbital and the aryl
π orbital. Herein, we synthesized a small series of novel biscarbazoles
bridged with permethylated oligosilanyl units (−[Si(CH3)2]n–, n = 1–4) and examined their spectroscopic properties in detail.
In the target molecules BCzSin, n = 2–4, the efficient σ–π conjugation
elevated the highest occupied molecular orbital energy level with
no influence on the lowest unoccupied molecular orbital. In the solid
state, the emission full width at half-maximum (fwhm) of all the compounds
narrowed significantly, while the emission efficiency increased and
the emission color of carbazole was retained. This research provided
a very simple and general way of subtly manipulating the electronic
properties of organic materials to construct an emissive color-retaining
system for multifunctional applications.
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Feng, Siyang; Zhou, Zhikuan; Xiang, Xiaoshuang; Feng, Hongjie; Qu, Zhirong; Lu, Hua (2020). Oligosilanyl-Bridged Biscarbazoles:
Structure, Synthesis, and Spectroscopic Properties. ACS Publications. Collection. https://doi.org/10.1021/acsomega.0c02559
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AUTHORS (6)
SF
Siyang Feng
ZZ
Zhikuan Zhou
XX
Xiaoshuang Xiang
HF
Hongjie Feng
ZQ
Zhirong Qu
HL
Hua Lu