Nonbifunctional Outer-Sphere Strategy Achieved Highly
Active α‑Alkylation of Ketones with Alcohols by N‑Heterocyclic Carbene Manganese (NHC-Mn)
Posted on 2019-09-16 - 19:13
The
unusual nonbifunctional outer-sphere strategy was successfully utilized
in developing an easily accessible N-heterocyclic
carbene manganese (NHC-Mn) system for highly active α-alkylation
of ketones with alcohols. This system was efficient for a wide range
of ketones and alcohols under mild reaction conditions, and also for
the green synthesis of quinoline derivatives. The direct outer-sphere
mechanism and the high activity of the present system demonstrate
the potential of nonbifunctional outer-sphere strategy in catalyst
design for acceptorless dehydrogenative transformations.
CITE THIS COLLECTION
DataCite
3 Biotech
3D Printing in Medicine
3D Research
3D-Printed Materials and Systems
4OR
AAPG Bulletin
AAPS Open
AAPS PharmSciTech
Abhandlungen aus dem Mathematischen Seminar der Universität Hamburg
ABI Technik (German)
Academic Medicine
Academic Pediatrics
Academic Psychiatry
Academic Questions
Academy of Management Discoveries
Academy of Management Journal
Academy of Management Learning and Education
Academy of Management Perspectives
Academy of Management Proceedings
Academy of Management Review
Lan, Xiao-Bing; Ye, Zongren; Huang, Ming; Liu, Jiahao; Liu, Yan; Ke, Zhuofeng (2019). Nonbifunctional Outer-Sphere Strategy Achieved Highly
Active α‑Alkylation of Ketones with Alcohols by N‑Heterocyclic Carbene Manganese (NHC-Mn). ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.9b03030
or
Select your citation style and then place your mouse over the citation text to select it.