Nanorod Manganese Oxide as an Efficient Heterogeneous
Catalyst for Hydration of Nitriles into Amides
Posted on 2019-08-31 - 20:13
Hydration of nitriles has been practically
used for the production
of amides, wherein the homogeneous catalysts including acids/bases
and metal complexes are generally employed. Here, we report that nanorod
manganese oxide (NR-MnO2) as a sustainable and low-cost
heterogeneous catalyst is highly active and selective for the hydration
of aromatic, heterocyclic, and aliphatic nitriles into the corresponding
amides. The catalytic properties of NR-MnO2 significantly
outperform that of commercial Pd/C and Ru/C catalysts and even the state-of-the-art homogeneous catalysts in the literature.
In the continuous recycling tests, the NR-MnO2 catalyst
exhibited excellent durability with negligible deactivation, which
offers a good opportunity for practical production of these chemicals
in the future.
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Wang, Hai; Wang, Yeqing; Xu, Hua; Zhou, Hang; Wang, Liang; Meng, Xiangju; et al. (2019). Nanorod Manganese Oxide as an Efficient Heterogeneous
Catalyst for Hydration of Nitriles into Amides. ACS Publications. Collection. https://doi.org/10.1021/acs.iecr.9b04128