Lithium and Sodium Ion Distributions in A2–x[W6I14] Structures
Posted on 2018-02-20 - 15:04
Ag2[W6I14] and A2–x[W6I14] compounds with A = Na, Li were prepared from binary
tungsten iodides (W3I12) and corresponding metal
iodides. Their crystal structures are analyzed on the basis of X-ray
diffraction data. 7Li and 23Na solid-state NMR
measurements reveal that Li+ and Na+ ions are
distributed over two sites in the respective structures. These results
shed some new light on Ax[M6I14] with A = alkali and M = Mo, W compounds being reported
with x = 1 and 2, which exhibit photophysical properties.
The lithium compound is an exception in the series of A2–x[W6I14] compounds, because
it is the only compound which is soluble in water.
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Hummel, Thorsten; Mos-Hummel, Agnieszka; Merkulova, Anna; Ströbele, Markus; Krishnamurthy, Arun; Kroeker, Scott; et al. (2018). Lithium and Sodium Ion Distributions in A2–x[W6I14] Structures. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.7b02948
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AUTHORS (7)
TH
Thorsten Hummel
AM
Agnieszka Mos-Hummel
AM
Anna Merkulova
MS
Markus Ströbele
AK
Arun Krishnamurthy
SK
Scott Kroeker
HM
Hans-Jürgen Meyer