Hybrid
Thin-Film Encapsulation for All-Solid-State
Thin-Film Batteries
Posted on 2020-02-28 - 21:45
All-solid-state thin-film
batteries have been actively investigated
as a power source for various microdevices. However, insufficient
research has been conducted on thin-film encapsulation, which is an
essential element of these batteries as solid electrolytes and Li
anodes are vulnerable to moisture in the atmosphere. In this study,
a hybrid thin-film encapsulation structure of hybrid SiOy/SiNxOy/a-SiNx:H/Parylene
is suggested and investigated. The water-vapor transmission rate of
hybrid thin-film encapsulation is estimated to be 4.9 × 10–3 g m–2·day–1, a value that is applicable to batteries as well as flexible solar
cells, thin-film transistor liquid-crystal display, and E-papers.
As a result of hybrid thin-film encapsulation, it is confirmed that
the all-solid-state thin-film batteries are stable even after 100
charge/discharge cycles in the air atmosphere for 30 days and present
a Coulombic efficiency of 99.8% even after 100 cycles in the air atmosphere.
These results demonstrate that the thin-film encapsulation structure
of hybrid SiOy/SiNxOy/a-SiNx:H/Parylene can be employed in thin-film batteries
while retaining long-term stability.
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Lee, HyunSeok; Lim, Keun Yong; Kim, Kwang-Bum; Yu, Jae-Woong; Choi, Won Kook; Choi, Ji-Won (2020). Hybrid
Thin-Film Encapsulation for All-Solid-State
Thin-Film Batteries. ACS Publications. Collection. https://doi.org/10.1021/acsami.9b20471
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AUTHORS (6)
HL
HyunSeok Lee
KL
Keun Yong Lim
KK
Kwang-Bum Kim
JY
Jae-Woong Yu
WC
Won Kook Choi
JC
Ji-Won Choi