Highly Stereoselective Additions of Tin
Enolates to Nitroalkenes and
Subsequent Conversion of the Nitro
Group into a Nitrile
Posted on 2005-04-28 - 00:00
Sn-chelated glycine ester enolates are efficient nucleophiles for highly stereoselective 1,4-additions toward nitroolefins and subsequent reductions
of the nitronate intermediates formed, giving rise to amino acid nitriles.
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Mendler, Barbara; Kazmaier, Uli (2016). Highly Stereoselective Additions of Tin
Enolates to Nitroalkenes and
Subsequent Conversion of the Nitro
Group into a Nitrile. ACS Publications. Collection. https://doi.org/10.1021/ol050129j
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