Hierarchical Self-Assembly of an Alkynylplatinum(ll)
Bzimpy-Functionalized Metallacage via Pt···Pt and π–π
Interactions

Yang, Hai-Bo

Hierarchical Self-Assembly of an Alkynylplatinum(ll) Bzimpy-Functionalized Metallacage via Pt···Pt and π–π Interactions

Posted on 2017-12-16 - 19:49

A new discrete supramolecular metallacage functionalized with an alkynylplatinum(ll) 2,6-bis(benzimidazole-2′-yl)-pyridine (bzimpy) moiety has been successfully constructed via coordination-driven self-assembly. A study on the hierarchical self-assembly behavior of the obtained metallacage revealed that it displayed a solvent-induced emission switch accompanied by enhancement of the emission intensity as a result of the change in intermolecular Pt···Pt and π–π interactions. More interestingly, the metallacage has been found to spontaneously self-assemble into a transparent metallogel at room temperature without a heating–cooling process.

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Zhang, Ying; Zhou, Qi-Feng; Huo, Gui-Fei; Yin, Guang-Qiang; Zhao, Xiao-Li; Jiang, Bo; et al. (2017). Hierarchical Self-Assembly of an Alkynylplatinum(ll) Bzimpy-Functionalized Metallacage via Pt···Pt and π–π Interactions. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.7b02777

https://doi.org/10.1021/acs.inorgchem.7b02777

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