From Food Additive to High-Performance Heavy Metal
Adsorbent: A Versatile and Well-Tuned Design
Version 3 2018-02-22, 05:33
Version 2 2016-08-30, 15:02
Version 1 2016-08-01, 19:55
Posted on 2018-02-22 - 05:33
A biosourced,
cross-linked hydrogel-type heavy metal adsorbent is presented. Various
factors such as the highly efficient chemical interactions, the various
network structures, the decreased energy consumption during cross-linking,
and the negligible amount of generated waste are considered when designing
the adsorbent. The widely applied, naturally occurring food additive
δ-gluconolactone is studied as a building block for the adsorbent.
Aminolysis reactions were applied to form linear dimer precursors
between diamines and δ-gluconolactones. The abundant hydroxyl
groups on the dimers from δ-gluconolactone were fully exploited
by using them as the cross-linking sites for reactions with ethylenediaminetetraacetic
dianhydride, a well-known metal-chelating moiety. The versatility
of the adsorbent and its metal-ion binding capacity is well tuned
using dimers with different structures and by controlling the feed
ratios of the precursors. Buffers with different pH values were used
as the conditioning media to examine the swelling properties and the
mechanical properties of the hydrogels, revealing that both properties
can be controlled. High heavy metal chelating performance of the adsorbent
was determined by isothermal adsorption kinetics, titration, and thermal
gravimetric analysis. The adsorbent exhibits an outstanding chelating
ability toward the three tested heavy metals (Cu(II), Co(II), Ni(II)),
and the maximum adsorption capacity (qm ∼ 121 mg·g–1) is higher than that
of the majority of the reported biosourced adsorbents.
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Hua, Geng; Odelius, Karin (2016). From Food Additive to High-Performance Heavy Metal
Adsorbent: A Versatile and Well-Tuned Design. ACS Publications. Collection. https://doi.org/10.1021/acssuschemeng.6b01109
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AUTHORS (2)
GH
Geng Hua
KO
Karin Odelius
KEYWORDS
energy consumptionadsorbent exhibitsFood Additivefeed ratiosdimer precursorsmetal adsorbentHigh-Performance Heavy Metal AdsorbentAminolysis reactionschelating abilitygravimetric analysisδ- gluconolactonepH valuesnetwork structuresmetal-chelating moietyWell-Tuned Designmetal-ion binding capacityhydroxyl groupsadsorption kineticsbiosourced adsorbentschemical interactionsfood additive δ- gluconolactoneconditioning mediacross-linked hydrogel-typebuilding blockadsorption capacitymetal chelating performanceδ- gluconolactonesVarious factorscross-linking sitesethylenediaminetetraacetic dianhydride