Fe(III)-Catalyzed Hydroallylation of Unactivated Alkenes
with Morita–Baylis–Hillman Adducts
Posted on 2018-02-19 - 14:04
An
Fe(III)-catalyzed hydroallylation of unactivated alkenes with
Morita–Baylis–Hillman adducts via an Fe-catalyzed process
is described. A variety of alkenes, including mono-, di-, and trisubstituted
alkenes, could all smoothly convert to structural diversified cinnamates
in this protocol. Interestingly, when the hydroxyl-containing alkenes
were used, various lactones could be rapidly assembled. Moreover,
this protocol could be applied to late-stage functionalization of
natural products.
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Qi, Jifeng; Zheng, Jing; Cui, Sunliang (2018). Fe(III)-Catalyzed Hydroallylation of Unactivated Alkenes
with Morita–Baylis–Hillman Adducts. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b00108
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