Experimental and Theoretical Study for Vapor Phase
Aldol Condensation of Methyl Acetate and Formaldehyde over Alkali
Metal Oxides Supported on SBA-15
Version 2 2018-02-19, 13:34
Version 1 2018-02-17, 15:48
Posted on 2018-02-19 - 13:34
Alkali
metal oxides supported on SBA-15, M/SBA-15 (M = Li, Na,
K, Rb, and Cs), prepared by the impregnation method were characterized
and tested for the aldol condensation of methyl acetate and formaldehyde
to methyl acrylate (MA). M/SBA-15 catalysts are active for the formation
of MA while the support is inert. The supported alkali metals react
with hydroxyl groups on SBA-15 by replacing the H atoms and generate
weak and medium basic sites. The latter plays an important role in
promoting the reaction. Coke formation results in deactivation of
Cs/SBA-15, and the deactivated catalyst can be regenerated by burning
off the coke. Two possible reaction pathways for the formation of
MA were explored using quantum calculations. The predicated activity
for M/SBA-15 is consistent with the experimental observations. A pathway
with adsorbed enol molecule as an intermediate was suggested to be
predominant for the formation of MA.
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He, Teng; Qu, Yixin; Wang, Jidong (2018). Experimental and Theoretical Study for Vapor Phase
Aldol Condensation of Methyl Acetate and Formaldehyde over Alkali
Metal Oxides Supported on SBA-15. ACS Publications. Collection. https://doi.org/10.1021/acs.iecr.7b02841
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