Expanding the Scope of Surface Grafted Polymers Using Electroinitiated
Polymerization
Posted on 2020-06-25 - 11:38
The
ability to rapidly modify the surface of materials is a powerful
means of tailoring interfaces and interphases for a variety of applications.
In this work, we demonstrate the extensive scope of an electrochemically
mediated surface modification technique, able to install a range of
surface grafted polymers of varying polarity and functionality. The
irreversible reduction of aryldiazonium salts initiates polymer growth
and provides a “priming layer” for the polymers to attach
to, covalently anchoring them to the surface. We show the broad applicability
of this technique through polymerization of 19 acrylate monomers,
as well as a noncarbonyl bearing monomer species, styrene. Surface
bound films were characterized using FT-IR, ellipsometry, and water
contact angle.
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Randall, James
D.; Stanfield, Melissa K.; Eyckens, Daniel J.; Pinson, Jean; Henderson, Luke C. (2020). Expanding the Scope of Surface Grafted Polymers Using Electroinitiated
Polymerization. ACS Publications. Collection. https://doi.org/10.1021/acs.langmuir.0c00444