Dinitrogen
Splitting and Functionalization in the
Coordination Sphere of Rhenium
Posted on 2014-05-14 - 00:00
[ReCl3(PPh3)2(NCMe)] reacts with
pincer ligand HN(CH2CH2PtBu2)2 (HPNP) to five coordinate rhenium(III)
complex [ReCl2(PNP)]. This compound cleaves N2 upon reduction to give rhenium(V) nitride [Re(N)Cl(PNP)], as the
first example in the coordination sphere of Re. Functionalization
of the nitride ligand derived from N2 is demonstrated by
selective C–N bond formation with MeOTf.
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Klopsch, Isabel; Finger, Markus; Würtele, Christian; Milde, Bastian; Werz, Daniel B.; Schneider, Sven (2016). Dinitrogen
Splitting and Functionalization in the
Coordination Sphere of Rhenium. ACS Publications. Collection. https://doi.org/10.1021/ja502759d
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AUTHORS (6)
IK
Isabel Klopsch
MF
Markus Finger
CW
Christian Würtele
BM
Bastian Milde
DW
Daniel B. Werz
SS
Sven Schneider