Differentially Substituted Phosphines via Decarbonylation
of Acylphosphines
Posted on 2017-03-29 - 21:18
A new route to phosphines was developed
by a method that features
a “pre-join and transform” process that proceeds via
acylphosphine intermediates that may be readily prepared from carboxylic
acids and disubstituted phosphines. The efficient decarbonylations
of these acylphosphines using a nickel catalyst delivered the corresponding
phosphines. This method shows that the carboxyl group can play a role
similar to halides or triflates for introducing a substituted phosphorus
atom on an aromatic ring.
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Yu, Rongrong; Chen, Xingyu; Martin, Stephen F.; Wang, Zhiqian (2017). Differentially Substituted Phosphines via Decarbonylation
of Acylphosphines. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b00579
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AUTHORS (4)
RY
Rongrong Yu
XC
Xingyu Chen
SM
Stephen F. Martin
ZW
Zhiqian Wang