Diboron-Catalyzed Dehydrative Amidation of Aromatic
Carboxylic Acids with Amines

Saito, Susumu

Diboron-Catalyzed Dehydrative Amidation of Aromatic Carboxylic Acids with Amines

Posted on 2018-07-18 - 18:38

Tetrakis(dimethylamido)diboron and tetrahydroxydiboron are herein reported as new catalysts for the synthesis of aryl amides by catalytic condensation of aromatic carboxylic acids with amines. The developed protocol is both simple and highly efficient over a broad range of substrates. This method thus represents an attractive approach for the use of diboron catalysts in the synthesis of amides without having to resort to stoichiometric or additional dehydrating agents.

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Sawant, Dinesh N.; Bagal, Dattatraya B.; Ogawa, Saeko; Selvam, Kaliyamoorthy; Saito, Susumu (2018). Diboron-Catalyzed Dehydrative Amidation of Aromatic Carboxylic Acids with Amines. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b01480

https://doi.org/10.1021/acs.orglett.8b01480

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