Coupling of Carboxylic Acids with Ynamides and Subsequent
Rearrangement for the Synthesis of Imides/Amides

Cui, Sunliang

Coupling of Carboxylic Acids with Ynamides and Subsequent Rearrangement for the Synthesis of Imides/Amides

Posted on 2018-08-10 - 11:19

A coupling of carboxylic acids with ynamides and subsequent rearrangement for the synthesis of imides and amides is reported. The carboxylic acids could couple with ynamides to form α-acyloxyenamide followed by sulfonyl group migration and Mumm rearrangement to furnish the amides. Additionally, the products could be subjected to further rearrangement to deliver β-keto amides. This metal-free process represents an interesting method for chemical bonds cleavage and regeneration. Furthermore, divergent transformation of products were conducted to deliver an array of compounds.

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Shen, Yangyong; Li, Qi; Xu, Gang; Cui, Sunliang (2018). Coupling of Carboxylic Acids with Ynamides and Subsequent Rearrangement for the Synthesis of Imides/Amides. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b02134

https://doi.org/10.1021/acs.orglett.8b02134

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