Copper
Vanadate (Cu3V2O8): (Mo, W) Doping
Insights to Enhance Performance as an Anode
for Photoelectrochemical Water Splitting
Posted on 2020-07-07 - 14:46
Molybdenum (Mo) and
tungsten (W) doping in copper vanadate (Cu3V2O8) gives important insights into
the modulation of carrier mobility and charge separation efficiency.
Mo and W atoms have more valence electrons than vanadium(V), providing
extra electrons to the host lattice of Cu3V2O8 (CVO) resulting in raising the Fermi level wherein
impurity energy levels will act as donors. Doped samples have shown
current densities of ∼0.6 mA cm–2, which
is 3 times higher than that of pristine CVO, i.e., 0.18 mA cm–2. Mo-doped CVO showed an excellent stability for 4
h with 6.8% loss in current density.
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Pulipaka, Supriya; Boni, Nikhila; Meduri, Praveen (2020). Copper
Vanadate (Cu3V2O8): (Mo, W) Doping
Insights to Enhance Performance as an Anode
for Photoelectrochemical Water Splitting. ACS Publications. Collection. https://doi.org/10.1021/acsaem.0c00780