Copper-Catalyzed C(sp2)–S Coupling
Reactions for the Synthesis of Aryl Dithiocarbamates with Thiuram
Disulfide Reagents
Posted on 2017-10-16 - 19:41
An
efficient protocol for the copper-catalyzed preparation of aryl
dithiocarbamates from aryl iodides and inexpensive, environmentally
benign tetraalkylthiuram disulfides was developed. The features of
mild reaction conditions, high yields, and broad substrate scope render
this new approach synthetically attractive for the preparation of
potentially biologically active compounds.
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Dong, Zhi-Bing; Liu, Xing; Bolm, Carsten (2017). Copper-Catalyzed C(sp2)–S Coupling
Reactions for the Synthesis of Aryl Dithiocarbamates with Thiuram
Disulfide Reagents. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b02911
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