Conversion
of Ethanol via C–C Splitting on
Noble Metal Surfaces in Room-Temperature Liquid-Phase

Teng, Xiaowei

Conversion of Ethanol via C–C Splitting on Noble Metal Surfaces in Room-Temperature Liquid-Phase

Version 2 2019-06-06, 11:48

Version 1 2019-06-05, 15:03

Posted on 2019-06-06 - 11:48

Rh-catalyzed decomposition of ethanol into CO₂ and CH₄ via C–C bond splitting is reported in room-temperature liquid phase under atmospheric pressure. Mechanistic investigations show that C–C bond splitting of ethanol on the noble metal surface is rapid, and CO₂ forms through the oxidation of α-CH_xO and β-CH_x fragments after C–C bond splitting, while CH₄ forms through the hydrogenation of β-CH_x utilizing H atoms from −OH, β-CH_x, and α-CH_xOH fragments.

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Yang, Guangxing; Farsi, Lida; Mei, Yuhan; Xu, Xing; Li, Anyin; Deskins, N. Aaron; et al. (2019). Conversion of Ethanol via C–C Splitting on Noble Metal Surfaces in Room-Temperature Liquid-Phase. ACS Publications. Collection. https://doi.org/10.1021/jacs.8b13115

https://doi.org/10.1021/jacs.8b13115

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