Co3O4 Nanosheets Preferentially
Growing (220) Facet with a Large Amount of Surface Chemisorbed Oxygen
for Efficient Oxidation of Elemental Mercury from Flue Gas
Posted on 2020-06-27 - 17:18
Oxygen vacancies can capture and
activate gaseous oxygen, forming
surface chemisorbed oxygen, which plays an important role in the Hg0 oxidation process. Fine control of oxygen vacancies is necessary
and a major challenge in this field. A novel method for facet control
combined with morphology control was used to synthesize Co3O4 nanosheets preferentially growing (220) facet to give
more oxygen vacancies. X-ray photoelectron spectroscopy (XPS) results
show that the (220) facet has a higher Co3+/Co2+ ratio, leading to more oxygen vacancies via the Co3+ reduction
process. Density functional theory (DFT) calculations confirm that
the (220) facet has a lower oxygen vacancy formation energy. Furthermore,
scanning electron microscopy (SEM) and transmission electron microscopy
(TEM) results suggest that Co3O4 nanosheets
yield more defects during the synthesis process. These results are
the reasons for the greater number of oxygen vacancies in Co3O4 nanosheets, which is confirmed by electron energy loss
spectroscopy (EELS), Raman spectroscopy, and photoluminescence (PL)
spectroscopy. Therefore, Co3O4 nanosheets show
excellent Hg0 removal efficiency over a wide temperature
range of 100–350 °C at a high gas hourly space velocity
(GHSV) of 180 000 h–1. Additionally, the
catalytic efficiency of Co3O4 nanosheets is
still greater than 83%, even after 80 h of testing, and it recovers
to its original level after 2 h of in situ thermal treatment at 500
°C.
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Zhu, Hongda; Song, Xinxin; Han, Xiangkai; Zhang, Xiaopeng; Bao, Junjiang; Zhang, Ning; et al. (2020). Co3O4 Nanosheets Preferentially
Growing (220) Facet with a Large Amount of Surface Chemisorbed Oxygen
for Efficient Oxidation of Elemental Mercury from Flue Gas. ACS Publications. Collection. https://doi.org/10.1021/acs.est.0c03427
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AUTHORS (7)
HZ
Hongda Zhu
XS
Xinxin Song
XH
Xiangkai Han
XZ
Xiaopeng Zhang
JB
Junjiang Bao
NZ
Ning Zhang
GH
Gaohong He
KEYWORDS
oxygen vacancy formation energyHg 0 oxidation processEELSFlue Gas Oxygen vacanciesXPSPLfacetCo 3 O 4 nanosheetsHg 0 removal efficiencyGHSVCo 3 O 4 nanosheets showTEMSEMDFTscanning electron microscopytransmission electron microscopyoxygen vacanciesCo 3 O 4 Nanosheets PreferentiallySurface Chemisorbed OxygenX-ray photoelectron spectroscopyelectron energy loss spectroscopysurface chemisorbed oxygen