Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal
Synthesis of Open-Framework Borogermanate and Galloborate
Posted on 2017-10-18 - 18:18
Under solvothermal/surfactant-thermal
conditions, two new open-framework borogermanate and galloborate,
centrosymmetric (Hdima)2[Ge5B3O15(OH)] (1; dima = dimethylamine) and noncentrosymmetric
Na4Ga3B4O12(OH) (2), were obtained and characterized. Compound 1 contains an unusual basket-shaped Ge5B3O18(OH) cluster and displays a 3D open-framework layered structure.
Compound 2 shows an interrupted 3,4-connected network
constructed by alternately linked BO3 units and Ga3+ ions and displays weak second-harmonic-generation response.
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Yu, Su-Juan; Gu, Xiang-Yu; Deng, Ting-Ting; Huang, Jian-Hao; Cheng, Jian-Wen; Yang, Guo-Yu (2017). Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal
Synthesis of Open-Framework Borogermanate and Galloborate. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.7b02328
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AUTHORS (6)
SY
Su-Juan Yu
XG
Xiang-Yu Gu
TD
Ting-Ting Deng
JH
Jian-Hao Huang
JC
Jian-Wen Cheng
GY
Guo-Yu Yang