Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines

Vicente, Rubén

Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines

Posted on 2011-04-01 - 00:00

The mechanism of carboxylate-assisted ruthenium(II)-catalyzed direct alkylations of ketimines with unactivated alkyl halides was probed through experimental studies. The remarkable chemoselectivity of the broadly applicable catalyst also enabled direct alkylations among others on H₂O or under solvent-free reaction conditions.

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Ackermann, Lutz; Hofmann, Nora; Vicente, Rubén (2016). Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines. ACS Publications. Collection. https://doi.org/10.1021/ol200366n

https://doi.org/10.1021/ol200366n

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