Borata-Alkene Derived Syntheses of (F5C6)2B‑Substituted Bis(indenyl) Group 4 Metal
Complexes

Erker, Gerhard

Borata-Alkene Derived Syntheses of (F₅C₆)₂B‑Substituted Bis(indenyl) Group 4 Metal Complexes

Version 2 2016-08-16, 14:27

Version 1 2016-07-27, 13:56

Posted on 2016-07-30 - 00:00

An indene based borata-alkene was used as a reagent for the synthesis of B(C₆F₅)₂-functionalized group 4 bent-metallocene complexes. The respective borata-alkene was prepared by HB(C₆F₅)₂ hydroboration of dimethylbenzofulvene followed by deprotonation with lithium tetramethylpiperidide. Treatment of CpTiCl₃ or CpZrCl₃ with the borata-alkene gave the respective [(C₆F₅)₂B-indenyl]CpMCl₂ bent-metallocene complexes. Both were characterized by X-ray diffraction. The boryl-functionalized metallocenes gave active ethene or propene polymerization catalysts, respectively, upon activation with triethylaluminum.

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Kohrt, Sonja; Kehr, Gerald; Daniliuc, Constantin G.; Rojas, René S.; Rieger, Bernhard; Troll, Carsten; et al. (2016). Borata-Alkene Derived Syntheses of (F₅C₆)₂B‑Substituted Bis(indenyl) Group 4 Metal Complexes. ACS Publications. Collection. https://doi.org/10.1021/acs.organomet.6b00427

https://doi.org/10.1021/acs.organomet.6b00427

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