Bio-Based Polyesters with High Glass-Transition Temperatures
and Gas Barrier Properties Derived from Renewable Rigid Tricyclic
Diacid or Tetracyclic Anhydride
Posted on 2020-06-18 - 07:03
Novel tricyclic diacid
(TCDA) and tetracyclic anhydride (TCAH)
were synthesized from renewable furan to generate a series of bio-based
polyesters via melt polymerization (MP) of TCDA with
seven linear α,ω-diols and ring-opening polymerization
(ROP) of TCAH with three different epoxides. NMR and single-crystal
X-ray revealed a unique rigid W-shaped skeleton of TCDA and TCAH,
which was readily converted in diester units to the stable configuration
during polymerization. The multicyclic rigid structure imparts high
glass-transition temperature (Tg) comparable
to petrochemical polymers with the MP polyesters reaching up to 109
°C and ROP polyesters reaching up to 174 °C. In addition,
the rigid tricyclic moiety attributes to superior gas barrier properties
of the 2,5-furandicarboxylic acid-based polyester, which are significantly
better than that of current bio-based polyester poly(butylene succinate)
and polylactide. The outstanding heat tolerance and gas barrier properties
of these multicyclic polyesters appear to be promising as substitutes
for common industrial petrochemical-based polyesters.
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Zhang, Haiyan; Zhou, Guangyuan; Jiang, Min; Zhang, Houyu; Wang, Honghua; Wu, Yuanpeng; et al. (2020). Bio-Based Polyesters with High Glass-Transition Temperatures
and Gas Barrier Properties Derived from Renewable Rigid Tricyclic
Diacid or Tetracyclic Anhydride. ACS Publications. Collection. https://doi.org/10.1021/acs.macromol.0c00344
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AUTHORS (7)
HZ
Haiyan Zhang
GZ
Guangyuan Zhou
MJ
Min Jiang
HZ
Houyu Zhang
HW
Honghua Wang
YW
Yuanpeng Wu
RW
Rui Wang
KEYWORDS
Tetracyclic Anhydride Novel tricyclic diacidTricyclic DiacidTCDAsingle-crystal X-rayNMRgas barrier propertiesglass-transition temperaturering-opening polymerizationmulticyclic polyestersdiester unitsheat tolerancetricyclic moiety attributesT gROP polyestersHigh Glass-Transition Temperaturesbio-based polyestersMP polyestersGas Barrier Properties DerivedW-shaped skeletonpetrochemical-based polyestersTCAHtetracyclic anhydrideBio-Based Polyesterspetrochemical polymers