Aerobic Copper-Catalyzed
Synthesis of (E)‑Vinyl Sulfones by Direct
C–S Bond Oxidative Coupling

Pan, Yuanjiang

Aerobic Copper-Catalyzed Synthesis of (E)‑Vinyl Sulfones by Direct C–S Bond Oxidative Coupling

Version 2 2019-08-19, 18:44

Version 1 2019-07-29, 21:30

Posted on 2019-08-19 - 18:44

Copper-catalyzed aerobic oxidative C–S bond coupling reaction between thiophenols and aryl-substituted alkenes for (E)-vinyl sulfones synthesis is reported here. With air utilized as a green oxidant, this transformation not only produces various vinyl sulfones in moderate to good yields but also possesses a simple and ecofriendly system. To clarify the mechanism, kinetic experiments has been investigated.

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Liang, Xiao; Xiong, Mingteng; Zhu, Heping; Shen, Kexin; Pan, Yuanjiang (2019). Aerobic Copper-Catalyzed Synthesis of (E)‑Vinyl Sulfones by Direct C–S Bond Oxidative Coupling. ACS Publications. Collection. https://doi.org/10.1021/acs.joc.9b01400

https://doi.org/10.1021/acs.joc.9b01400

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