Access toward Fluorenone Derivatives through Solvent-Free
Ruthenium Trichloride Mediated [2 + 2 + 2] Cycloadditions

Ratovelomanana-Vidal, Virginie

Access toward Fluorenone Derivatives through Solvent-Free Ruthenium Trichloride Mediated [2 + 2 + 2] Cycloadditions

Version 2 2016-10-31, 17:05

Version 1 2016-10-21, 20:03

Posted on 2016-10-21 - 00:00

An efficient and practical route for the preparation of highly substituted fluorenones and analogues via solvent-free ruthenium trichloride mediated [2 + 2 + 2] cycloaddition of α,ω-diynes and alkynes has been developed. This green chemistry approach involves a solventless and atom-economical catalytic process to generate densely functionalized fluorenones and related derivatives of high synthetic utility.

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Ye, Fei; Haddad, Mansour; Michelet, Véronique; Ratovelomanana-Vidal, Virginie (2016). Access toward Fluorenone Derivatives through Solvent-Free Ruthenium Trichloride Mediated [2 + 2 + 2] Cycloadditions. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.6b02840

https://doi.org/10.1021/acs.orglett.6b02840

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