The effect of a synthetic saponite
surface on the “in-water”
dehydration reaction of diol was examined using 4-formyl-1-methylquinolinium
salt (MQu+) as a substrate. The equilibrium between aldehyde
(MQu+-Aldehyde) and diol (MQu+-Diol) was affected
by the surrounding environment. The equilibrium behavior was observed
by 1H nuclear magnetic resonance (NMR) and UV–vis
absorption measurements. Although MQu+ was completely in
the form of MQu+-Diol in water, the equilibrium almost
shifted to the MQu+-Aldehyde side when MQu+ was
adsorbed on the saponite surface in water. In addition, the MQu+-Aldehyde ratio depended on the negative charge density of
saponite. The factors that determine MQu+-Aldehyde: MQu+-Diol ratio were discussed from the thermodynamic analysis
of the system. These data indicate that the electrostatic interaction
between the charged saponite surface and MQu+ stabilized
the aldehyde side enthalpically and destabilized it entropically.
The major reason for these results is considered to be the difference
in adsorption stabilization between MQu+-Aldehyde and MQu+-Diol on saponite surfaces.