Ultradeep Removal
of Acetaldehyde from Ethanol through
Catalytic Hydrogenation with Highly Dispersed Ag Nanoparticles Supported
on Phenyl-Modified SiO2
posted on 2023-11-09, 19:34authored byYicheng Ye, Qiaohong Zhang, Dezhong Xie, Chen Chen, Fan Li, Hu Wang, Shun Zhang, Wei Zhang
Ethanol-based drinks and disinfectants are widely consumed
around
the world. Acetaldehyde (AA) is the main impurity in ethanol, which
is also a representative volatile organic compound (VOC). Increased
attention should be paid to the potential harm caused by AA in ethanol
due to the significant increase of AA exposure even in nondrinkers.
With Ag nanoparticles (NPs) being supported on the phenyl group-modified
silica (Ag/Ph-SiO2) as the catalyst, which was prepared
by a simple one-pot reverse-phase microemulsion method, a catalytic
hydrogenation removal strategy has been illustrated in the present
work to ultradeeply remove AA in ethanol. The introduction of phenyl
groups facilitated the distribution of Ag NPs, the formation of the
pore structure, and the improvement of the surface affinity to AA
molecules, which are beneficial for the adsorption and conversion
of AA in ethanol. The AA content in ethanol could be controlled to
be below 0.1 ppm at 90 °C in 5 h under 3 MPa H2 pressure.
The safety of ethanol-based products is believed to be greatly improved
with the present technology.