ol403156r_si_001.pdf (2.84 MB)
Total Synthesis of Sandresolide B and Amphilectolide
journal contribution
posted on 2014-01-03, 00:00 authored by Ingrid
T. Chen, Irina Baitinger, Lucas Schreyer, Dirk TraunerThe total synthesis
of the diterpenoids sandresolide B and amphilectolide
from a common furan building block is presented. Key steps include
palladium-mediated carbonylation, lanthanide catalyzed ring closure,
Myers alkylation, intramolecular Friedel–Crafts acylation,
photooxygenation, and a Kornblum–DeLaMare rearrangement.
